Isoprene oxidation by nitrate radical: alkyl nitrate and secondary organic aerosol yields
نویسندگان
چکیده
منابع مشابه
Global secondary organic aerosol from isoprene oxidation
[1] Inclusion of isoprene as a source of secondary organic aerosol (SOA) in a global model increases the global burden of SOA from all sources by more than a factor of two. The isoprene source substantially increases SOA concentrations in the free troposphere, because isoprene, and, more importantly, isoprene’s oxidation products, have much greater concentrations at higher altitudes than other ...
متن کاملSecondary organic aerosol (SOA) formation from reaction of isoprene with nitrate radicals (NO3)
Secondary organic aerosol (SOA) formation from the reaction of isoprene with nitrate radicals (NO3) is investigated in the Caltech indoor chambers. Experiments are performed in the dark and under dry conditions (RH<10%) using N2O5 as a source of NO3 radicals. For an initial isoprene concentration of 18.4 to 101.6 ppb, the SOA yield (defined as the ratio of the mass of organic aerosol formed to ...
متن کاملSecondary Organic Aerosol Formation and Organic Nitrate Yield from NO3 Oxidation of Biogenic Hydrocarbons
The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m(3) indoor Teflon chamber. By making in situ measurements of the nitrat...
متن کاملLink between isoprene and secondary organic aerosol (SOA): Pyruvic acid oxidation yields low volatility organic acids in clouds
[1] Aqueous-phase oxidation (in clouds and aerosols) is a potentially important source of organic aerosol and could explain the atmospheric presence of oxalic acid. Methylglyoxal, a water-soluble product of isoprene, oxidizes further in the aqueous phase to pyruvic acid. Discrepancies in the literature regarding the aqueous-phase oxidation of pyruvic acid create large uncertainties in the inclo...
متن کاملSecondary organic aerosol formation from isoprene photooxidation.
Recent work has shown that the atmospheric oxidation of isoprene (2-methyl-1,3-butadiene, C5H8) leads to the formation of secondary organic aerosol (SOA). In this study, the mechanism of SOA formation by isoprene photooxidation is comprehensively investigated, by measurements of SOA yields over a range of experimental conditions, namely isoprene and NOx concentrations. Hydrogen peroxide is used...
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ژورنال
عنوان ژورنال: Atmospheric Chemistry and Physics
سال: 2009
ISSN: 1680-7324
DOI: 10.5194/acp-9-6685-2009